All kick-off times in GMT.
- « Fri, Jun 7 |
- Tue, Jun 11, 2013
| 13' | Radamel Falcao (pen) | 1 - 0 | |
| 45' | Teófilo Gutiérrez | 2 - 0 | |
| 70' | Carlos Zambrano |
| 4' | 0 - 1 | Sergio Agüero (pen) | |
| 17' | Segundo Castillo | 1 - 1 | |
| 87' | Javier Mascherano |
| 2' | Alexis Sánchez | 1 - 0 | |
| 16' | Eduardo Vargas | 2 - 0 | |
| 16' | Eduardo Vargas | 3 - 0 | |
| 18' | Alexis Sánchez | 4 - 0 | |
| 32' | 4 - 1 | Marcelo Moreno | |
| 32' | 4 - 2 | Marcelo Moreno | |
| 90' +1' | Arturo Vidal | 5 - 2 | |
| 90' +2' | Arturo Vidal | 6 - 2 |