All kick-off times in GMT.
- « Sat, Aug 18 |
- Sun, Aug 19, 2012
- | Mon, Aug 20 »
| 7' | 0 - 1 | Rubén Castro | |
| 26' | 0 - 2 | Jorge Molina | |
| 31' | 0 - 3 | Beñat | |
| 47' | Oscar de Marcos | 1 - 3 | |
| 67' | Mikel San Jose | 2 - 3 | |
| 76' | Mikel San Jose | 3 - 3 | |
| 80' | 3 - 4 | Pozuelo | |
| 86' | 3 - 5 | Jorge Molina |
| 4' | Carles Puyol | 1 - 0 | |
| 9' | 1 - 1 | Gonzalo Castro | |
| 11' | Lionel Messi | 2 - 1 | |
| 16' | Lionel Messi | 3 - 1 | |
| 41' | Pedro | 4 - 1 | |
| 84' | David Villa | 5 - 1 |
| 5' | Nabil El Zhar | 1 - 0 | |
| 22' | 1 - 1 | Arda Turan |