All kick-off times in GMT.
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- Sun, May 19, 2013
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| FT | Dundee United | 0 - 4 | Celtic |
| FT | Ross County | 1 - 0 | Inverness Caledonian Thistle |
| FT | St Johnstone | 2 - 0 | Motherwell |
| FT | Levante | 2 - 3 | Rayo Vallecano |
| FT | Deportivo La Coruña | 2 - 0 | Espanyol |
| 17:00 | Real Zaragoza | v | Athletic Bilbao |
| 19:00 | Barcelona | v | Real Valladolid |
| FT | Atalanta | 2 - 2 | Chievo Verona |
| FT | Bologna | 0 - 0 | Genoa |
| 18:45 | AS Roma | v | Napoli |
| 18:45 | Cagliari | v | Lazio |
| 18:45 | Internazionale | v | Udinese |
| 18:45 | Palermo | v | Parma |
| 18:45 | Siena | v | AC Milan |
| 18:45 | Torino | v | Catania |
| 18:45 | US Pescara | v | Fiorentina |
| FT | Alania Vladikavkaz | 1 - 0 | Dinamo Moscow |
| FT | PFK Samara Kryliya Sovetov | 3 - 1 | FK Rubin Kazan |
| FT | Zenit St Petersburg | 3 - 1 | Volga Nizhny Novgorod |
| FT | Elazigspor | 0 - 0 | Sivasspor |
| FT | Genclerbirligi | 2 - 2 | Bursaspor |
| 16:00 | Eskisehirspor K | v | Antalyaspor |
| 16:00 | Kayserispor | v | Besiktas |
| 15:15 | PAOK Salonika | v | Giannina |
| 17:30 | Asteras Tripoli | v | Atromitos |
| FT | BK Hacken | 2 - 2 | Gefle IF |
| FT | Osters IF | 2 - 3 | AIK |
| 2nd | Djurgarden | 1 - 0 | Halmstad |
| 2nd | IFK | 1 - 0 | Kalmar FF |
| 2nd | IFK Norrkoping | 1 - 1 | Atvidabergs FF |
| 17:00 | New York Red Bulls | v | Los Angeles |
| 21:00 | DC United | v | Kansas City |
| May 20, 02:30 | Chivas USA | v | Real Salt Lake |
| 39' | Independiente | 1 - 0 | San Martín de San Juan |
| 18:15 | Unión de Santa Fe | v | River Plate |
| 23:30 | All Boys | v | San Lorenzo |
| HT | Universidad Católica | 1 - 0 | Universidad de Chile |
| 20:00 | Municipal Iquique | v | O'Higgins |
| 22:30 | Rangers de Talca | v | Huachipato |
| 18:30 | Danubio F.C. | v | Bella Vista |
| 18:30 | Juventud | v | Progreso |
| 18:30 | Liverpool | v | El Tanque Sisley |
| 19:00 | Peñarol | v | Wanderers |
| 20:15 | Independiente Medellín | v | Patriotas F.C. |
| 22:30 | Once Caldas | v | Itagüí |
| May 20, 00:45 | Deportivo Pasto | v | Independiente Santa Fe |
| Group A | |||
|---|---|---|---|
| FT | Alianza Lima | 1 - 0 | UTC |
| TBD | César Vallejo | v | Universitario de Deportes |
| TBD | Club Sportivo Cienciano | v | Melgar FBC |
| FT | José Gálvez | 4 - 1 | Unión Comercio |
| TBD | Juan Aurich | v | Pacífico FC |
| 33' | León de Huánuco | 0 - 0 | Inti Gas Deportes |
| FT | San Martin | 0 - 3 | Sporting Cristal |
| FT | Sport Huancayo | 1 - 1 | Real Garcilaso |
| 19:00 | Sp. Carapeguá | v | Sol de América |
| 22:20 | Olimpia | v | Guaraní |
| 17:00 | Manta F.C. | v | LDU Quito |
| 19:30 | Deportivo Quevedo | v | El Nacional |
| 21:45 | Barcelona | v | Emelec |
| 19:30 | Petrolero | v | La Paz |
| 20:00 | Aurora | v | Blooming |
| 20:00 | Bolívar | v | Nacional Potosí |
| 20:00 | Oriente Petrolero | v | Wilstermann |
| 20:00 | San José | v | Universitario de Sucre |