All kick-off times in GMT.
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- Sun, May 19, 2013
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| FT | Dundee United | 0 - 4 | Celtic |
| FT | Ross County | 1 - 0 | Inverness Caledonian Thistle |
| FT | St Johnstone | 2 - 0 | Motherwell |
| FT | Levante | 2 - 3 | Rayo Vallecano |
| FT | Deportivo La Coruña | 2 - 0 | Espanyol |
| FT | Real Zaragoza | 1 - 2 | Athletic Bilbao |
| FT | Barcelona | 2 - 1 | Real Valladolid |
| FT | Alania Vladikavkaz | 1 - 0 | Dinamo Moscow |
| FT | PFK Samara Kryliya Sovetov | 3 - 1 | FK Rubin Kazan |
| FT | Zenit St Petersburg | 3 - 1 | Volga Nizhny Novgorod |
| FT | Elazigspor | 0 - 0 | Sivasspor |
| FT | Genclerbirligi | 2 - 2 | Bursaspor |
| FT | Eskisehirspor K | 3 - 1 | Antalyaspor |
| FT | Kayserispor | 2 - 0 | Besiktas |
| FT | BK Hacken | 2 - 2 | Gefle IF |
| FT | Osters IF | 2 - 3 | AIK |
| FT | Djurgarden | 1 - 0 | Halmstad |
| FT | IFK | 2 - 0 | Kalmar FF |
| FT | IFK Norrkoping | 2 - 1 | Atvidabergs FF |
| FT | New York Red Bulls | 1 - 0 | Los Angeles |
| FT | DC United | 1 - 1 | Kansas City |
| May 20, 02:30 | Chivas USA | v | Real Salt Lake |
| FT | Independiente | 3 - 1 | San Martín de San Juan |
| FT | Unión de Santa Fe | 2 - 2 | River Plate |
| 74' | All Boys | 0 - 1 | San Lorenzo |
| FT | Universidad Católica | 3 - 0 | Universidad de Chile |
| FT | Municipal Iquique | 2 - 1 | O'Higgins |
| FT | Rangers de Talca | 5 - 2 | Huachipato |
| FT | Danubio F.C. | 4 - 1 | Bella Vista |
| FT | Juventud | 4 - 2 | Progreso |
| FT | Liverpool | 1 - 1 | El Tanque Sisley |
| FT | Peñarol | 0 - 0 | Wanderers |
| FT | Independiente Medellín | 2 - 1 | Patriotas F.C. |
| FT | Once Caldas | 1 - 2 | Itagüí |
| 17' | Deportivo Pasto | 0 - 0 | Independiente Santa Fe |
| Group A | |||
|---|---|---|---|
| FT | Alianza Lima | 1 - 0 | UTC |
| FT | César Vallejo | 0 - 1 | Universitario de Deportes |
| FT | Club Sportivo Cienciano | 0 - 0 | Melgar FBC |
| FT | José Gálvez | 4 - 1 | Unión Comercio |
| 103' | Juan Aurich | 0 - 0 | Pacífico FC |
| FT | León de Huánuco | 0 - 0 | Inti Gas Deportes |
| FT | San Martin | 0 - 3 | Sporting Cristal |
| FT | Sport Huancayo | 1 - 1 | Real Garcilaso |
| FT | Manta F.C. | 1 - 1 | LDU Quito |
| FT | Deportivo Quevedo | 1 - 1 | El Nacional |
| FT | Barcelona | 2 - 0 | Emelec |
| FT | Aurora | 3 - 1 | Blooming |
| FT | Bolívar | 2 - 1 | Nacional Potosí |
| FT | Oriente Petrolero | 6 - 2 | Wilstermann |
| FT | San José | 2 - 1 | Universitario de Sucre |