All kick-off times in GMT.
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- Wed, Jan 23, 2013
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| FT-Pens | Nice | (2)2 - 2(4) | AS Nancy Lorraine |
| FT | Montpellier | 2 - 3 | Sochaux |
| FT | Raon-l'Etape | 1 - 0 | FC Istres |
| FT-Pens | Meaux | (3)0 - 0(5) | St Etienne |
| FT-Pens | Venissieux Minguettes | (4)0 - 0(3) | Le Poire SV |
| FT | Bastia CA | 1 - 3 | Brest |
| FT | Bordeaux Stade | 0 - 3 | Lens |
| FT | Moulins | 1 - 2 | Bordeaux |
| FT | Paris Saint-Germain | 3 - 1 | Toulouse |
| FT | Cruzeiro POA | 0 - 0 | Santa Cruz |
| FT | Cerámica | 1 - 2 | Internacional |
| FT | Novo Hamburgo | 0 - 2 | São José-POA |
| FT | Passo Fundo | 1 - 1 | Juventude |
| FT | Pelotas | 1 - 3 | Esportivo-RS |