All kick-off times in GMT.
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- Sat, Jan 12, 2013
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| FT | Braintree Town | 3 - 2 | AFC Telford United |
| FT | Hereford United | 3 - 3 | Alfreton Town |
| FT | Lincoln City | 2 - 4 | Newport County |
| FT | Mansfield Town | 0 - 2 | Kidderminster Harriers |
| FT | Nuneaton Town | 1 - 1 | Forest Green Rovers |
| FT | Dumbarton | 2 - 0 | Partick Thistle |
| FT | Dunfermline Athletic | 1 - 3 | Airdrie United |
| FT | Falkirk | 0 - 1 | Greenock Morton |
| FT | Hamilton Academical | 2 - 1 | Cowdenbeath |
| FT | Livingston | 2 - 1 | Raith Rovers |
| FT | Albion Rovers | 0 - 3 | Queen of the South |
| FT | East Fife | 2 - 2 | Brechin City |
| FT | Forfar Athletic | 2 - 1 | Ayr United |
| FT | Stenhousemuir | 0 - 0 | Stranraer |
| FT | Annan Athletic | 2 - 1 | Montrose |
| FT | Clyde | 2 - 1 | Stirling Albion |
| FT | Elgin City | 3 - 4 | East Stirlingshire |
| FT | Queen's Park | 0 - 0 | Peterhead |
| FT | Rangers | 4 - 2 | Berwick Rangers |
| FT | Real Valladolid | 3 - 1 | Mallorca |
| FT | Espanyol | 1 - 0 | Celta Vigo |
| FT | Osasuna | 0 - 0 | Real Madrid |
| FT | Valencia | 2 - 0 | Sevilla FC |
| FT | Troyes | 1 - 2 | Lyon |
| FT | AS Nancy Lorraine | 2 - 2 | Lille |
| FT | Evian Thonon Gaillard | 0 - 2 | Brest |
| FT | Montpellier | 2 - 0 | Lorient |
| FT | Stade Rennes | 0 - 2 | Bordeaux |