All kick-off times in GMT.
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- Sat, Dec 8, 2012
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| FT | Arsenal | 2 - 0 | West Bromwich Albion |
| FT | Aston Villa | 0 - 0 | Stoke City |
| FT | Southampton | 1 - 0 | Reading |
| FT | Sunderland | 1 - 3 | Chelsea |
| FT | Swansea City | 3 - 4 | Norwich City |
| FT | Wigan Athletic | 2 - 2 | Queens Park Rangers |
| FT | Kilmarnock | 1 - 3 | Celtic |
| FT | Heart of Midlothian | 2 - 0 | Aberdeen |
| FT | Inverness Caledonian Thistle | 3 - 0 | Hibernian |
| FT | Motherwell | 3 - 2 | Ross County |
| FT | St Mirren | 1 - 1 | St Johnstone |
| FT | Annan Athletic | 2 - 3 | Queen's Park |
| FT | Berwick Rangers | 1 - 1 | Peterhead |
| FT | Elgin City | 2 - 1 | Clyde |
| FT | Rangers | 2 - 0 | Stirling Albion |
| FT | Real Sociedad | 1 - 1 | Getafe |
| FT | Malaga | 4 - 0 | Granada |
| FT | Real Valladolid | 2 - 3 | Real Madrid |
| FT | Osasuna | 0 - 1 | Valencia |
| FT | Almeria | 0 - 1 | Lugo |
| FT | Barcelona B | 1 - 1 | Elche |
| FT | Guadalajara | 5 - 1 | Numancia |
| FT | Las Palmas | 4 - 0 | Huesca |
| FT | CD Sabadell | 2 - 2 | Murcia |
| FT | Brescia | 2 - 2 | Reggina |
| FT | Crotone | 0 - 0 | Lanciano |
| FT | Grosseto | 3 - 0 | Pro Vercelli |
| FT | Hellas Verona | 3 - 1 | Ascoli |
| FT | Novara | 3 - 1 | Padova |
| FT | Spezia | 3 - 2 | Bari |
| FT | Ternana | 3 - 2 | Juve Stabia |
| FT | Vicenza | 3 - 3 | Livorno |
| FT | Paris Saint-Germain | 4 - 0 | Evian Thonon Gaillard |
| FT | AS Nancy Lorraine | 1 - 1 | Valenciennes |
| FT | Montpellier | 3 - 0 | AC Ajaccio |
| FT | Sochaux | 1 - 1 | Lille |
| FT | Stade Rennes | 2 - 2 | Brest |
| FT | Troyes | 1 - 1 | Nice |
| FT | Reims Ste-Anne | 0 - 5 | Caen |
| FT | St-Amand | 1 - 3 | Le Havre AC |
| FT | Limonest | 0 - 1 | Arles |
| FT-Pens | AS Monaco | 0 - 0 | Bourg-Peronnas |
| FT | Arras | 1 - 0 | Angers |
| FT | Bordeaux Stade | 1 - 0 | Niort |
| FT | Tarbes | 0 - 5 | Nimes |
| FT | Aurillac | 0 - 1 | FC Istres |
| FT | Evreux | 0 - 1 | Le Mans |
| FT | Mondeville | 0 - 1 | Chateauroux |
| FT | RKC Waalwijk | 2 - 0 | NEC Nijmegen |
| FT | ADO Den Haag | 1 - 1 | PEC Zwolle |
| FT | AZ Alkmaar | 0 - 0 | Willem II Tilburg |
| FT | Ajax Amsterdam | 2 - 0 | FC Groningen |
| FT | FK Amkar Perm' | 0 - 2 | PFK Samara Kryliya Sovetov |
| FT | Kuban Krasnodar | 0 - 0 | Alania Vladikavkaz |
| FT | Lokomotiv Moscow | 0 - 1 | Volga Nizhny Novgorod |
| FT | Kasimpasa | 2 - 2 | Genclerbirligi |
| FT | Gaziantepspor | 0 - 2 | Karabukspor |
| FT | Bursaspor | 1 - 0 | Orduspor |
| FT | Sivasspor | 1 - 3 | Galatasaray |
| FT | RAEC Bergen Mons | 0 - 5 | Anderlecht |
| FT | Cercle Brugge KSV | 1 - 1 | OH Leuven |
| FT | KAA Gent | 0 - 2 | Waasland-Beveren |
| FT | KV Kortrijk | 1 - 2 | Zulte-Waregem |
| FT | KV Mechelen | 2 - 1 | KSC Lokeren |
| FT | FC Trenkwalder Admira | 0 - 3 | SV Josko Ried |
| FT | SK Sturm Graz | 1 - 1 | SV Salzburg |
| FT | SV Mattersburg | 1 - 0 | FC Magna Wr. Neustadt |
| FT | Wolfsberger AC | 3 - 6 | Austria Vienna |
| FT | Ballinamallard Utd | 1 - 3 | Linfield |
| FT | Ballymena | 1 - 2 | Portadown |
| FT | Cliftonville | 3 - 1 | Coleraine |
| FT | Dungannon Swifts | 3 - 0 | Donegal Celtic |
| FT | Glenavon | 4 - 1 | Lisburn Distillery |
| FT | Glentoran | 1 - 1 | Crusaders |
| FT | Argentinos Juniors | 1 - 3 | Newell's Old Boys |
| FT | Boca Juniors | 2 - 1 | Godoy Cruz de Mendoza |
| FT | Atletico Rafaela | 0 - 3 | Vélez Sarsfield |
| FT | Belgrano de Córdoba | 1 - 0 | Estudiantes La Plata |
| FT | Lanús | 0 - 0 | San Lorenzo |
| FT | Newcastle Jets | 0 - 2 | Central Coast Mariners |
| FT | Wellington Phoenix FC | 1 - 2 | Sydney FC |
| FT | Western Sydney FC | 1 - 0 | Brisbane Roar |