All kick-off times in GMT.
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- Tue, Nov 27, 2012
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| FT | Aberdeen | 2 - 3 | Inverness Caledonian Thistle |
| FT | Dundee United | 1 - 2 | Motherwell |
| FT | Ross County | 0 - 0 | St Mirren |
| FT | Osasuna | 2 - 0 | Sporting Gijon |
| FT | Rayo Vallecano | 0 - 0 | Las Palmas |
| FT | Real Betis | 3 - 0 | Real Valladolid |
| FT | Real Sociedad | 2 - 2 | Cordoba |
| FT | Malaga | 0 - 1 | Cacereno |
| FT | Real Madrid | 3 - 0 | Alcoyano |
| FT | Borussia Dortmund | 1 - 1 | Fortuna Düsseldorf |
| FT | Eintracht Frankfurt | 1 - 3 | Mainz |
| FT | Hamburg SV | 3 - 1 | Schalke 04 |
| FT | Hannover 96 | 2 - 0 | SpVgg Greuther Furth |
| FT | Dynamo Dresden | 0 - 0 | VfR Aalen |
| FT | Kaiserslautern | 1 - 1 | SSV Jahn Regensburg |
| FT | TSV 1860 Munich | 1 - 0 | SC Paderborn 07 |
| FT | VfL Bochum | 1 - 3 | FSV Frankfurt |
| FT | Wolfsberger AC | 1 - 1 | SK Sturm Graz |