All kick-off times in ET.
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- Fri, Nov 9, 2012
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| FT | FC Cologne | 0 - 0 | MSV Duisburg |
| FT | FC Erzgebirge Aue | 1 - 1 | TSV Eintracht Braunschweig |
| FT | SV Sandhausen | 1 - 6 | Hertha Berlin |
| FT | Ajaccio GFCO | 1 - 1 | Sedan |
| FT | Angers | 0 - 0 | Niort |
| FT | Arles | 0 - 3 | Stade Laval |
| FT | Dijon FCO | 2 - 1 | Nimes |
| FT | FC Istres | 1 - 0 | Le Mans |
| FT | Guingamp | 0 - 0 | Tours |
| FT | Le Havre AC | 1 - 3 | Clermont Foot |
| FT | Nantes | 1 - 1 | Chateauroux |
| FT | Belgrano de Córdoba | 0 - 0 | Argentinos Juniors |
| FT | Newell's Old Boys | 0 - 0 | Quilmes |
| FT | Vélez Sarsfield | 2 - 1 | Godoy Cruz de Mendoza |
| FT | Moroka Swallows | 1 - 1 | Chippa United |