All kick-off times in GMT.
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- Sat, Nov 3, 2012
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| FT | Dundee | 1 - 0 | Heart of Midlothian |
| FT | Hibernian | 2 - 1 | St Mirren |
| FT | Kilmarnock | 1 - 2 | Inverness Caledonian Thistle |
| FT | Ross County | 2 - 1 | Aberdeen |
| FT | St Johnstone | 1 - 3 | Motherwell |
| FT | Malaga | 1 - 2 | Rayo Vallecano |
| FT | Barcelona | 3 - 1 | Celta Vigo |
| FT | Real Madrid | 4 - 0 | Real Zaragoza |
| FT | Valencia | 2 - 0 | Atletico Madrid |
| FT | Mirandes | 3 - 0 | Barcelona B |
| FT | Numancia | 1 - 1 | Villarreal |
| FT | Murcia | 0 - 1 | Girona |
| FT | Racing Santander | 2 - 1 | AD Alcorcon |
| FT | Brescia | 1 - 0 | Ternana |
| FT | Empoli | 2 - 1 | Pro Vercelli |
| FT | Grosseto | 2 - 1 | Ascoli |
| FT | Livorno | 2 - 1 | Bari |
| FT | Novara | 0 - 1 | Cittadella |
| FT | Padova | 1 - 1 | Cesena |
| FT | Reggina | 1 - 1 | Varese |
| FT | Spezia | 2 - 1 | Crotone |
| FT | Vicenza | 0 - 1 | Lanciano |
| FT | Borussia Dortmund | 0 - 0 | VfB Stuttgart |
| FT | Borussia Monchengladbach | 1 - 1 | SC Freiburg |
| FT | Hannover 96 | 2 - 0 | FC Augsburg |
| FT | Nurnberg | 1 - 0 | VfL Wolfsburg |
| FT | TSG Hoffenheim | 3 - 2 | Schalke 04 |
| FT | Hamburg SV | 0 - 3 | Bayern Munich |
| FT | Paris Saint-Germain | 1 - 2 | St Etienne |
| FT | Evian Thonon Gaillard | 0 - 2 | Lille |
| FT | Nice | 2 - 1 | AS Nancy Lorraine |
| FT | Stade Rennes | 1 - 0 | Stade de Reims |
| FT | Troyes | 1 - 1 | Montpellier |
| FT | Valenciennes | 3 - 1 | Sochaux |
| FT | Ajax Amsterdam | 0 - 2 | Vitesse Arnhem |
| FT | Willem II Tilburg | 1 - 5 | FC Utrecht |
| FT | PSV Eindhoven | 4 - 0 | SC Heracles Almelo |
| FT | FK Amkar Perm' | 0 - 3 | Kuban Krasnodar |
| FT | PFK Samara Kryliya Sovetov | 0 - 5 | Spartak Moscow |
| FT | Mordovia Saransk | 1 - 3 | FK Rubin Kazan |
| FT | Kayserispor | 3 - 0 | Karabukspor |
| FT | Akhisar Belediye | 1 - 2 | Fenerbahce |
| FT | Eskisehirspor K | 4 - 0 | Gaziantepspor |
| FT | KV Mechelen | 1 - 4 | Anderlecht |
| FT | Germinal Beerschot | 1 - 2 | Waasland-Beveren |
| FT | KAA Gent | 1 - 2 | Racing Genk |
| FT | KV Kortrijk | 4 - 1 | Lierse SK |
| FT | RAEC Bergen Mons | 3 - 2 | Cercle Brugge KSV |
| FT | Royal Charleroi SC | 0 - 2 | KSC Lokeren |
| FT | FC Magna Wr. Neustadt | 0 - 1 | FC Wacker Tirol |
| FT | SK Sturm Graz | 2 - 1 | Rapid Vienna |
| FT | SV Mattersburg | 1 - 1 | Wolfsberger AC |
| FT | SV Salzburg | 5 - 0 | FC Trenkwalder Admira |
| FT | Coleraine | 1 - 1 | Portadown |
| FT | Crusaders | 5 - 1 | Glenavon |
| FT | Donegal Celtic | 0 - 3 | Linfield |
| FT | Glentoran | 1 - 1 | Cliftonville |
| FT | Carmarthen | 2 - 1 | Airbus UK |
| FT | Port Talbot | 6 - 1 | Connah's Quay |
| FT | Prestatyn Town | 3 - 1 | Llanelli |
| FT | T.N.S. | 2 - 1 | Afan Lido |
| FT | Bala Town | 3 - 2 | Aberystwyth |
| FT | Argentinos Juniors | 1 - 1 | San Martín de San Juan |
| FT | Unión de Santa Fe | 2 - 2 | Estudiantes La Plata |
| FT | Boca Juniors | 3 - 1 | San Lorenzo |
| FT | Arsenal de Sarandí | 1 - 5 | Vélez Sarsfield |
| FT | Antofagasta | 1 - 2 | Colo Colo |
| FT | Cobresal | 2 - 2 | La Serena |
| FT | Palestino | 1 - 2 | Unión San Felipe |
| FT | Municipal Iquique | 2 - 4 | Unión Española |
| FT | Audax Italiano | 5 - 1 | O'Higgins |
| FT | Itagüí | 0 - 0 | Independiente Santa Fe |
| FT | Millonarios | 2 - 0 | Envigado |
| FT | Once Caldas | 0 - 2 | Atlético Nacional |
| FT | Deportes Tolima | 2 - 1 | Deportivo Pasto |
| Group B | |||
|---|---|---|---|
| FT | Unión Comercio | 1 - 2 | César Vallejo |
| FT | Alianza Lima | 2 - 1 | Juan Aurich |
| FT | Central Coast Mariners | 7 - 2 | Sydney FC |
| FT | Perth Glory | 3 - 2 | Newcastle Jets |
| FT | Brisbane Roar | 0 - 1 | Adelaide United |
| FT | Santa Tecla | 1 - 0 | Juventud Independiente |
| FT | Aguila | 1 - 3 | Atletico Marte |
| FT | CD FAS | 1 - 1 | Luis Angel Firpo |
| FT | Metapan | 1 - 2 | Universidad de El Salvador |