All kick-off times in GMT.
- « Sun, Oct 7 |
- Sat, Oct 20, 2012
- | Sun, Oct 21 »
| 11' | Gonzalo Higuaín | 1 - 0 | |
| 67' | Cristiano Ronaldo (pen) | 2 - 0 |
| 19' | 0 - 1 | Aritz Aduriz | |
| 26' | Roberto Soldado (pen) | 1 - 1 | |
| 30' | 1 - 2 | Aritz Aduriz | |
| 67' | Ander Herrera | ||
| 88' | Tino Costa | 2 - 2 | |
| 90' | Nelson Haedo Valdez | 3 - 2 |
| 3' | 0 - 1 | Jordi Alba | |
| 8' | 0 - 2 | Cristian Tello | |
| 18' | 0 - 3 | Lionel Messi | |
| 26' | Pizzi (pen) | 1 - 3 | |
| 37' | Alex Bergantiños | 2 - 3 | |
| 43' | 2 - 4 | Lionel Messi | |
| 47' | Pizzi | 3 - 4 | |
| 49' | Javier Mascherano | ||
| 77' | 3 - 5 | Lionel Messi | |
| 79' | Jordi Alba (og) | 4 - 5 |